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. Tên gọi khác: Axit Frohydric, HF, Frohydric acid
. Tổng quan Axit Frohydric – HF.
Đặc tính: Axit flohiđric là một dung dịch của hydrogen fluoride (HF) trong nước, Cùng với hydrogen fluoride, hydrofluoric acid là một nguồn flo quý giá, là chất tiền thân của nhiều dược phẩm, polymer (ví dụ Teflon), và phần lớn các chất tổng hợp có chứa flo. Người ta biết đến axit này nhiều nhất là khả năng hòa tan kính của nó do axit này tác dụng với SiO2, thành phần chính của kính. Quá trình hòa tan có thể miêu tả như sau:
SiO2(s) + 4HF(aq) → SiF4(g) + 2H2O(l)
SiO2(s) + 6HF(aq) → H2[SiF6](aq) + 2H2O(l)
Bởi tính chất phản ứng mạnh với kính, axit flohidric thường được lưu chứa trong các bình nhựa polyethylene hoặc Teflon. Nó cũng đặc trưng bởi khả năng hòa tan nhiều kim loại và oxit của các á kim.
. Ứng dụng:
Lọc dầu.
Trong một tiêu chuẩn nhà máy lọc dầu quá trình được gọi là ankyl hóa , isobutane Alkylated với trọng lượng phân tử thấp các alkene (chủ yếu là một hỗn hợp của propylen , butylen ) trong sự hiện diện của chất xúc tác acid mạnh có nguồn gốc từ acid HF. Chất xúc tác protonates các alkene (propylen, butylen) để sản xuất carbocations phản ứng , mà alkylate isobutane. Phản ứng này được thực hiện ở nhiệt độ nhẹ (0 và 30 ° C) trong một phản ứng hai giai đoạn.
fluoride trong môi trường, công nghệ thay thế đang được tìm kiếm. Florua vô cơ khác được chuẩn bị từ acid HF bao gồm sodium fluoride và hexafluoride uranium .
Chất ăn mòn và làm sạch
Khả năng của acid HF để hòa tan các oxit kim loại là cơ sở của một số ứng dụng. Nó loại bỏ các tạp chất oxit từ thép không gỉ, một quá trình được gọi là tẩy, và các tấm wafersilicon trong ngành công nghiệp chất bán dẫn. Về vấn đề này cũng được gọi là BHF, (khi đệm với Fluoride Amoni), và BOE (cho Oxide đệm Etch). Nó là một thành phần quan trọng của Wright Etch và HNA tương tự (HF + Nitric + Acetic Acid) etch. Theo cách tương tự, nó cũng được sử dụng để etch kính . Gel axit 5% đến 9% HF cũng thường được sử dụng để etch tất cả các phục hồi nha khoa gốm để cải thiện liên kết. Đối với lý do tương tự, pha loãng axít flohiđric là một thành phần của hộ gia đình tẩy vết gỉ và xe rửa"sạch bánh xe" các hợp chất. HF axit tấn công thủy tinh bằng cách phản ứng với silicon dioxide để tạo thành các florua silicon khí hoặc hòa tan trong nước. Quá trình này giải thể tiến hành như sau:
SiO 2 + 4 HF → SIF 4 (g) + 2 H 2 O
SiO 2 + 6 HF → H 2 SIF 6 + 2 H 2 O
Bởi vì khả năng hòa tan oxit sắt cũng như silica-chất gây ô nhiễm, axit HF được sử dụng trước khi vận hành nồi hơi sản xuất hơi nước áp suất cao.
Ứng dụng phá đá
Bởi vì khả năng của mình để hòa tan các oxit, axit HF là hữu ích cho việc giải thể các mẫu đá (thường là bột) trước khi phân tích. Theo cách tương tự, axit này được sử dụng trong macerations axit để trích xuất các hóa thạch hữu cơ từ các loại đá silicat. Fossiliferous đá có thể được nhúng trực tiếp vào acid, hoặc một bộ phim cellulose nitrate có thể được áp dụng (giải thể trong acetate amilic), tuân thủ các thành phần hữu cơ và cho phép đá bị giải thể xung quanh nó.
Pha loãng axít flohiđric (1-3% khối lượng) được sử dụng trong ngành công nghiệp dầu khí trong hỗn hợp với axit (HCl hoặc acid hữu cơ) để kích thích sản xuất của nước, dầu, và các giếng khí đốt đặc biệt, nơi đá sa thạch được tham gia
Acid HF cũng được sử dụng bởi một số nhà sưu tập các chai thủy tinh cổ để loại bỏ cái gọi là bệnh từ thủy tinh, gây ra bởi axit (thường là trong đất chai được chôn cất tại) tấn công các nội dung soda của kính.
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